Msystem integrated desmear electroless copper combines a statistically developed and proven primary metallization system to fit the needs of the printed circuit board industry. Electroless copper plating, however, offers advantages over electrolytic plating that make it the method of choice in certain cases. When an iron substrate is immersed in a solution of copper sulfate or silver nitrate, the iron dissolves while the copper or silver is plated out onto the surface of the substrate. Thus, the palladium sites for the catalytic surfaces needed for metal deposition was formed. Copper plating on plastic can also strengthen the part and produce a shine that makes it more aesthetically appealing, which. The electroless copper deposition process developed in this study may open up a new route of plating on plastics pop for printed circuit boards, electromagnetic interference shielding, and many. Electroless copper plating was carried out at room temperature for up to 5 min in a suf. As plated structures become smaller and substrates smoother. Us20143071a1 process for the electroless copper plating of. Uyemura products create substantial advantages in operation and. Electroless copper deposition with peg suppression for all copper flipchip connections tyler osborn,z nefertari galiba. Copper, cobalt, nickel, tin, and cadmium are also examples of electrolytic plating. Though the deposition rate of electroless copper solution was accelerated by 2,6.
We can even create a customized copper plating procedure for your companys specific metal plating. Cannon nemesis space saver connector features black electroless nickel plating for soldier worn applications itt cannons black electroless nickel is a rohscompliant, costeffective and sustainable plating alternative to cadmium. Pdf improved electroless copper coverage at low catalyst. The technology most commonly used today to accomplish this function is the electroless copper process. The following procedure was taken from the procedure manual found in the surface. Copper contamination of electroless nickel baths can be equally detrimental. We can also plate copper onto nonmetallic materials such as plastics. Circuposit electroless copper fullbuild electroless copper uniform, bright electroless copper activator activator 472 ionic palladium activator, activation of copper for electroless nickel electroless nickel duraposit mf 1110 ammonia, lead and cadmiumfree electroless nickel plating on plasticsfunctional. The reaction is accomplished when hydrogen is released by a reducing agent, normally sodium hypophosphite note. The electroless copper plating using sodium hypophosphite as the reductant and sodium. Uyemuras mission is the development of practical solutions to the competitive, operational and environmental challenges our customers face. In general, electroless plating is characterized by the selective reduction of metal ions only at the surface of a catalytic substrate immersed into an aqueous solution of said metal ions, with continued deposition on the substrate through the catalytic action of the deposit itself. I need to know how i should clean and or prep the surface for maybe a copper.
Electroless copper plating is a critical process in printed circuit board pcb manufacture where it is employed to make the through holes and vias of a pcb conductive for subsequent electroplating. Current distribution limitations lead to faster copper plating at the feature top and upper. A musthave for anyone in electroplating, including technicians, platers, plating researchers, and metal finishers, modern electroplating, fifth edition is also an excellent reference for electrical engineers and researchers in the automotive, data storage, and medical industries. Compared with the plating temperature y50 uc normally used in the alkaline copper bath, adopting a relatively lower temperature in this experiment was necessary to reduce the thickness of copper. A discussion started in 2001 but continuing through 2017. A stable bath is slow, but a higher rate bath can decompose at the drop of a hat.
Research drive, tempe, arizona plating tutorial for tong hsing, march 2009 build up of reacon products electroless plang tank is a closed chemical system by products from the reducon reacon build up in the tank electroless ni, orthophosphite ions accumulate hpo 3 2. Vertical electroless copper metallization macdermid. Plating on plastics and metal finishing technologies. Copper plating troubleshooting tips sharretts plating. The first stage of the process is a chemical desmear process designed for todays variety of special resin systems. Electroless copper plating is widely used for the fabrication of printed circuit boards and other electronic devices. Bottomup fill of copper in deep submicrometer holes by electroless plating shoso shingubara,z zengling wang, osamu yaegashi, ryo obata, hiroyuki sakaue, and takayuki takahagi graduate school of advanced sciences of matter, hiroshima university, higashihiroshima 7398530, japan. Kits 372 kb pdf read the instruction manual here 4 simple steps to brush plate your small parts 1. The typeof heating that is used in the plating process is also of great concern.
The bath is an aqueous solution of cupric sulphate, iminodiacetic acid, formaldehyde, and sodium hydroxide. In general commercial practice, thickness range from 0. Copper plating on plastic substrates is often used to make the plastic electrically conductive, which is a primary concern in the electronics industry. Electroless plating, also known as chemical or autocatalytic plating, is a nongalvanic plating method that involves several simultaneous reactions in an aqueous solution, which occur without the use of external electrical power. Electroless nickel plating electroless nickel offers greater uniformity than conventional electroplating. The operator clamps the production panels into the jigs. A high reliability, stressfree copper deposit for fpc. Plating with copper copper plating services copper. Sharretts plating company has developed an efficient copper plating process that can be used with various metal substrates.
Electroless copper plates much more slowly, and is a much more expensive process, than electrolytic copper plating. Chapter electroless copper in printed wiring board fabrication. The strike layer is electroless nickel, which is preferred to electroless copper because the copper polyimide bond degrades with time while the nickel polyimide bond does not degrade. Can anybody tell me the formula for electroless copper. Pdf new electroless copper plating bath using sodium. The mechanism of electroless metal plating is thoroughly studied only for relatively deep stages of autocatalytic reduction when the deposition process proceeds on a metal substrate 1, 7. In electroless technique many metals like nickel, copper, gold, silver, plating palladium and cobalt are being deposited. Advanced plating technologies is deeply involved within the surface finishing industry helping to set industry direction in education, process development and environmental stewardship. Electroless and electrolytic copper plating of glass. Macdermid alpha electronics solutions always innovating.
Electroless nickel with ptfe copper cadmium free electroless nickel titanium chrome free electroless nickel inconel lead free electroless nickel production capacity. Plating difficult substrates with electroless nickel. Ultem is a polyetherimide resin with a 30% glass content. Electroless copper plating on microcellular polyurethane foam. Electroless copper can provide a seed layer on a dielectric material for subsequent acid copper electroplating. Electroless nickel deposits are functional coatings and are rarely used for decorative purposes only. A fourthgeneration family owned and operated company, advanced plating technologies exemplifies the best in wisconsins businesses and entrepreneurship. Pdf in this article, the recent developments in electroless plating of copper, electroless bath formulation and effect of plating parameters have. Bottomup fill of copper in deep submicrometer holes by. Electroless nickel plating tanks can be heated internally or externally. In addition, electroless plating provides uniform thickness and deposits, especially in deep recesses, bores, and blind holes. Pdf recent progress in electroless plating of copper. Electroless plating is a method of plating metal by chemical rather than electrical means, in which the piece to be plated is immersed in a reducing agent that, when catalyzed by certain materials, changes metal ions to metal that forms a deposit on the piece.
Process for the electroless copper plating of metallic substrates download pdf. This is especially useful for doing touch ups, or gold plating, where the solution is expensive. Highend applications like plating of integrated circuit ic substrate interconnects require. Electroless nickel, alloy, composite and nano coatings a. Electroless copper plates uniformly over all surfaces, regardless of size and shape. In electroless copper plating, there is always a tugofwar between the deposition rate and bath stability. Electroless nickel plating is also known as chemical or autocatalytic nickel plating. Electroless nickel plating with low phosporous content exhibit low contact impedance. Chapter the fundamental aspects of electroless nickel plating. It is possible to combine the sensitizing and activating step together by. In 1950, a commercial electroless copper plating process was developed. Excellent adhesion of electroless plated copper seed layer on glass can be achieved by using the adhesive layer and annealing technology. The thin adhesive layer is nonconductive and can be easily removed from the area between. Working with our customers, we research, formulate, and deliver specialty chemicals for the most complex printed circuit board designs.
The frequency and amount of replenishment required will depend upon the baths deposition rate, as well as the workload ftgal being processed. Copper is consumed as the work being processed is plated, and requires frequent replenishment to keep the bath in chemical balance. Since all electroless nickel plating systems use a nickel alloy as the plating metal, different alloy solutions are required for different applications and for different base metals. Pdf in this paper, a new environment friendly electroless plating bath using sodium hypophosphite as reductant and nitrilotriacetic acid as. A study on the interfacial composition of the electroless. Electroless copper has been used widely for plating non conductors and in several. Electroless nickel plating with higher phospohorous content will have somewhat higher contact impedance but will have improved corrosion reistance. Electroless copper plating solutions comprised of 0. Electroless plating of silver plating process and the reaction mechanism plated film practice of electroless silver plating.
Electroless copper plating from an iminodiacetate bath 95 that the mechanism of electroless copper deposition from a new iminodiacetate ida bath is found to be fully explained by the mixed potential theory. Electroless cu plating is used in the electronics industry to obtain conductive layers on bare resins. Brush plating is a technique which allows you to plate a small area on a part without immersing it in a tank. Electroless plating is a chemical reaction of the part and the solution, usually heated, which plates the part extremely evenly. Comparison between electroplating and electroless on.
Electroless cu plating microelectronics applications. Advanced plating technologies plating, passivation and. Lack of agitation of the plating solution can also cause problems. Electroless copper plating an overview sciencedirect.
Chemical deposition of metallic films from aqueous solutions autocatalytic electroless plating displacement immersion. Electroless plating processes cost less, but only in terms of time and. Uyemura is an international chemistry company with core competencies in the development, testing and manufacture of plating chemistries for the electronics and metal finishing industries. A study of low temperature and low stress electroless copper. The electroplating of plastics follows the same cycle as that described for decorative chromium electroplating. Alternative technologies are available to accomplish the.
Electroless plating has increased in popularity due to improvements in solution stability, pretreatment cycles, reducing agents, and equipment. After each process step, the plastic is rinsed with water to prevent carryover of solution from one bath to another. Copper concentrations of 31 00 ppm will cause immersiondeposit on ferrous alloy parts, which in turn causes adhesion problems of the electroless nickel plate. The most common electroless nickel is deposited by the catalytic reduction of nickel ions with sodium hypophosphite in acid baths at ph 4. The brownells electroless nickel plating system deposits an alloy consisting of 87% per nickel, 12% phosphorous and 1% copper. Perhaps the greatest challenge facing the surface finisher is preparing various surfaces for electroless nickel plating.
This technology typically employs formaldehyde as a copper reducing agent and requires large amounts of water and energy. Always innovating macdermid alpha electronics solutions supplies innovative, environmentally sound products to a rapidly changing electronics marketplace. A major benefit of this approach over electroplating is that the power sources and plating baths are not needed, reducing the cost of production. Here, the authors have studied the effects of a dualcomplexed electroless copper bath, using both edta and triethanolamine tea. A sustainable electroless copper coating process was developed for plating automotive. D226 journal of the electrochemical society, 004651. Electroless copper zinc plating solution safety data sheet page 1 of 12 section 1. The industrial uses of electroless nickel especially the nickelphosphorus alloy has grown steadily during the last decade, because of its unique properties. I need to get together a process for plating nickel, preferably en on ultem 2300.